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All right guys I remember hating this back when I did second year in organic chemistry at the University of Waterloo, but I realized they still teach it, so we still got to teach it to you, you need the mo diagram for n2 plus now they could have asked you for the mo diagram for any of these atoms here or rather diatoms Li to be e2 f2 and e2 these are just the way that they teach you mo diagrams alright now here's the first thing you got to remember when you're asked for the mo diagram of a diatom like that there are two different mo diagrams you basically have to memorize for atoms from lithium to nitrogen it looks like this where you have your two s orbitals coming together to form a sigma 2 s and a sigma 2 s anti-bonding I shouldn't have drawn that there that's a mistake Sigma 2 s and Sigma 2 s antibonding your 2p orbitals come together to form these and yes you're just going to have to memorize these and the order you have a Sigma 2p and a Sigma 2p antibonding, and you also have a PI 2p and a PI 2p anti-bonding now there are two of those notice 6 orbitals became 6 orbitals at different energies this is just how mo diagrams work, and honestly I've never figured any reason for other than that's just the way it is, and we accept it so if you're asked for the mo diagram for n2 plus you're basically going to regurgitate this diagram let's see if we can do that well the two 2's orbitals come together to form a sigma 2 s and a sigma 2 s anti-bonding check my two peas come together to form a PI 2p and a Sigma 2p, and we need corresponding PI 2p anti-bonding and oops Sigma 2p anti-bonding it's ideal to draw in those funky lines if they always seem to show tu-tu-tu-tu-tu-tu q, and then you've got to fill it with electrons n2 + brings each n brings 5 electrons with it, so that makes 10, but we have a plus charge, so we're taking away one we need to fill this with 9 electrons now what I haven't shown you are that there's a 1s orbital that's already filled here but nonetheless in my valence shell I need nine electrons 1 2 3 4 5 6 notice that I'm spreading out the electrons, so there's one in each equivalent energy orbital before I start doubling up 7 8 9 now that's the mo diagram for n 2 plus you may be asked for something called the bond order which is the number of electrons in bonding orbitals minus the number of electrons and anti-bonding orbitals divided by 2 in the bonding orbitals I've got 1 2 3 4 5 6 electrons in anti-bonding orbitals I've got oops one thought back to bonding I didn't realize that was bonding one two three four five six seven I've got seven bonding electrons how many antibonding electrons one two and that's it when I do that my calculator I got a bond order of 2.5 a bond order with a point five in it isn't super stable and so n/2 plus probably isn't super stable FYI I told you this was the mo diagram you had to memorize for lithium to nitrogen the one for oxygen to neon is pretty much the same the only difference is that oxygen to...
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