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This document outlines a laboratory experiment designed to measure the hardness of water by titration using EDTA, detailing the preparation of solutions, titration procedures, and data recording.
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How to fill out Chemistry 201 Laboratory - Experiment 1: Hardness of Water by EDTA Titration

01
Collect all required materials: EDTA solution, water sample, indicator (e.g., Eriochrome Black T), buffer solution.
02
Measure a specific volume of the water sample (e.g., 50 mL) and place it in a clean flask.
03
Add a few drops of the indicator to the water sample; it should change color indicating the presence of hardness ions.
04
Prepare a buffer solution if required and add it to the sample to maintain a stable pH during titration.
05
Titrate the water sample with the EDTA solution, adding it slowly while swirling the flask.
06
Watch for the endpoint of titration, indicated by a color change (from red to blue or violet to blue, depending on pH).
07
Record the volume of EDTA used at the endpoint.
08
Calculate the hardness of water based on the volume of EDTA used and its concentration.

Who needs Chemistry 201 Laboratory - Experiment 1: Hardness of Water by EDTA Titration?

01
Chemistry students wanting to understand water hardness.
02
Environmental scientists studying water quality.
03
Researchers conducting studies on water treatment processes.
04
Industrial professionals involved in water testing and treatment.
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Water hardness can be measured using a procedure known as complexometric titration by adding a known concentration of the chelating agent EDTA through a burette to a sample containing an unknown amount of calcium and magnesium ions. EDTA reacts and captures these metal ions creating a larger metal complex.
Explanation: The amount of calcium carbonate or its equivalent in different calcium and magnesium salts that are present in a million parts of water by mass is considered the degree of hardness. It's measured in ppm.
*Conclusion: Hardness is the property which makes water to form an insoluble precipitate with soap and is primarily due to the presence of calcium and magnesium ions. Hard waters have no known adverse health effects and may be more palatable than soft waters.
This document describes the EDTA method for determining water hardness. EDTA (ethylene diammine tetra acetic acid) forms stable complexes with Ca2+ and Mg2+ ions. The water sample is titrated with a standardized EDTA solution using an indicator. The volume of EDTA used corresponds to the hardness of the water sample.
Water hardness is the measurement of the sum of molar concentrations of dissolved cations in the water. Thus, the more divalent cations dissolved in the water the “harder” the water. These divalent ions can impact the taste of water and they usually present in water in the forms of carbonate and bicarbonate complexes.
From this experiment, we can conclude that, ∙​ ​Rockwell hardness of a steel specimen increases with increase in the carbon content, keeping the cooling rate constant. ∙​ ​Rockwell hardness of a steel specimen increases with increase in the cooling rate, keeping the carbon content constant.
The EDTA method is a complexometric titration technique used to determine the hardness of water. Hard water contains high concentrations of calcium (Ca²⁺) and magnesium (Mg²⁺) ions. EDTA (ethylenediaminetetraacetic acid) is a chelating agent that forms stable complexes with these metal ions.
The hardness of good quality water should not exceed 250 mg/L measured as calcium carbonate equivalents. Waters softer than 30 to 50 mg/L may be corrosive to piping depending on pH, alkalinity and dissolved oxygen. The major hardness in water is due to Ca², Mg² ions and other divalent ions.

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Chemistry 201 Laboratory - Experiment 1 focuses on determining the hardness of water using a titration method involving EDTA (ethylenediaminetetraacetic acid) as a chelating agent to quantify the concentration of metal ions in a water sample.
All students enrolled in the Chemistry 201 course are required to complete and file the results for Experiment 1 as part of their laboratory assignments.
Students must accurately record all data during the experiment, including initial and final titration readings, calculations of hardness, and any observations. They should fill out the lab report template provided by the instructor.
The purpose of this experiment is to teach students the principles of titration and to assess the hardness of water, which can affect both domestic and industrial applications.
Students must report their titration data, including the volume of EDTA used, calculations for hardness in mg/L (as CaCO3), any deviations from expected results, and a conclusion summarizing their findings.
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