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Despite this we were able to demonstrate the influence of reducing agents on the rate of formation of ruthenium oligonucleotide products. In future work we will address the question of which base s in the oligonucleotide the ruthenium is coordinated to by tandem mass spectrometry. Both ions contain either 5- or 6-coordinate ruthenium depending on whether the oligonucleotide is functioning as a unidentate or bidentate ligand. 3 and 912. 9 attribut...
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