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Experiment 15: Atomic Orbitals, Bond Length, and Molecular Orbitals
Introduction
Molecular orbitals result from the mixing of atomic orbitals that overlap during the bonding process
allowing the delocalization
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How to fill out molecular orbitals:
01
Start by determining the total number of electrons available for filling the molecular orbitals. This can be done by adding up the number of valence electrons from each individual atom in the molecule.
02
Next, arrange the molecular orbitals according to their energy levels. The lowest energy orbitals are filled first, following the Aufbau principle, which states that electrons fill up lower energy levels before moving to higher energy levels.
03
Fill the orbitals with electrons, pairing them up until each orbital contains a maximum of two electrons with opposite spins. This is known as the Pauli exclusion principle.
04
Follow Hund's rule, which states that when filling degenerate orbitals (orbitals with the same energy level), electrons will occupy different orbitals with parallel spins, filling each orbital with one electron before pairing them up.
05
Continue filling the orbitals until all the electrons are distributed among them, making sure to obey the octet rule, if applicable, for main group elements.
Who needs molecular orbitals?
01
Chemists and researchers studying the properties and behavior of molecules require a thorough understanding of molecular orbitals.
02
Molecular orbitals are particularly important in the field of quantum chemistry, as they provide insight into the electronic structure and bonding of molecules.
03
Understanding molecular orbitals is essential for predicting and interpreting chemical reactions, as well as explaining various aspects of molecular properties, such as stability, reactivity, and spectroscopic behavior.
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What is molecular orbitals?
Molecular orbitals are regions in a molecule where electrons are most likely to be found. They are formed by the overlap of atomic orbitals from different atoms in a molecule.
Who is required to file molecular orbitals?
Scientists, researchers, and chemists who are studying the structure and properties of molecules are required to calculate and analyze molecular orbitals.
How to fill out molecular orbitals?
To fill out molecular orbitals, one needs to use computational chemistry software to perform calculations on the atomic orbitals of the atoms in a molecule and analyze the resulting molecular orbitals.
What is the purpose of molecular orbitals?
The purpose of molecular orbitals is to understand the bonding and electronic structure of molecules, which helps in predicting their reactivity and properties.
What information must be reported on molecular orbitals?
The information reported on molecular orbitals includes the energy levels, electron density, and shape of the molecular orbitals.
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