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Deciphering the Role of Internal Donors in Shaping Heterogeneous ZieglerNatta Catalysts Based on NonEmpirical Structural Determination Joo Marcos da Silveira, Hiroki Chikuma,, Gentoku Takasao, Toru Wada, Patchanee Chammingkwan, and Toshiaki Taniike*, Graduate School of Advanced Science and Technology, Japan Advanced Institute of Science and Technology, 11 Asahidai, Nomi, Ishikawa 9231292, JapanDivision of Physical Science and Engineering, King Abdullah University

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