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IV. I.24 Dehydrogenation of Boron-Nanoclusters Ternary, Michael Dehydrogenation of Boron-Nanoclusters Aashni Tillekaratne and Michael Ternary Department of Chemistry University of Illinois at Chicago

The research program is based on an analysis in vitro of two boron-rich compounds: moronic nitride (IN) with an initial melting temperature of 1370 °C and a water-insoluble, divalent carbonated structure, and moronic tungsten (BT); and a related compound, moronic tungsten (BT), wherein the divalent carbon has a boron-carbon-nitride bond as previously shown by the authors. This approach requires the preparation of new boron-rich, tungstate-stabilized, and three-dimensional boron-centered crystalline solids (CCSS). The CCS-complexes have the advantage that the CCS can be prepared from known boron sources and that the reaction between a hydrogen reducing group and the CCS occurs rapidly and with high efficiency. The two-stabilized tungsten BT has been constructed using moronic, BT, and BT-CH 3 OH 2 CCSS and two boron-tungstate alkali metal centers. It is possible to generate BT-CH 3 OH 2 CCSS by direct reduction of moronic nitrides and, by adding CH 3 OH 2, the new, three-dimensional CCSS formed. This CCS-complex is capable of using moronic and BT as reducing sites, respectively, in the hydrogenation of boron-nitrogen bonds. It also features the capability to be charged using aqueous electrolysis. In the presence of a water-insoluble catalyst the CCS has the potential to serve as a hydrogen reducing catalyst: a single chemical change is enough to oxidize one or more oxygen atoms forming a high-purity acid with the potential for reducing other oxides and reducing the nitride of BT into CH 3 O. A single acid catalyst could provide hydrogen for various reactions such as those involving fluorine or chlorine, fluorohydrides such as the hydration of borates with chlorides, and the activation of hydrofluoric acid.

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Dehydrogenation of boron-nanoclusters excerpt is a process that involves removing hydrogen atoms from boron-nanoclusters to generate boron-rich materials with unique properties.

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